Research article new design of zno nanorod and nanowirebased no 2 roomtemperature sensors prepared by hydrothermal method vo thanh duoc,1 dang thi thanh le,1 nguyen duc hoa,1 nguyen van duy,1 chu manh hung,1 hugo nguyen,2 and nguyen van hieu3,4 1international training institute for materials science itims, hanoi university of science and. Therefore, most efforts have been focused to obtain ptype zno materials. The development of phosphor devices free of heavy metal or rare earth elements is an important issue for environmental reasons and energy efficiency. Zno nanostructures, defects, and devices materials today. Anh thu do,a ho truong giang,a do van huong,a pham quang ngan,a giang hong thai,a do thi thua and tran dai lamb we synthesized zno architectures, including nanorods, porous plates, and. Znobased solar cells are suitable candidates for costeffective and environmentally friendly energy conversion devices. Onedimensional zno nanostructures have great potential applications in the fields of optoelectronic and sensor devices. Zno tcotype thin films, all prepared by solgel method. The alingan and zno materials systems have proven to be one of the scientifically and technologically important areas of development over the past 15 years, with applications in uvvisible optoelectronics and in highpower highfrequency microwave devices.
Concluding sections treat bandgap engineering, processing and zno nanostructures and nanodevices. Zno nanoparticle synthesis zno nanoparticle synthesis methods were adapted from beek et al. Of interest to device engineers, physicists, and semiconductor and solid state scientists in general. Pdf pznongan heterostructure zno lightemitting diodes. In materials science, zno is often called a iivi semiconductor because zinc and oxygen belong. Zno materials have being researched in recent 30 years as a hot topic. The high electron mobility, high thermal conductivity, wide and direct band gap and large exciton binding energy make zno. Gan and znobased materials and devices pdf free download. If you own the to this book and it is wrongfully on our website, we offer a simple dmca procedure to remove your content from our site. The alingan and zno materials systems have proven to be one of the scientifically and technologically important areas of development over the past 15 years, with applications in uvvisible optoelectronics and in highpowerhighfrequency microwave devices. Gan and znobased materials and devices springer series. Influence of sb doping on the structural, optical and.
The pace of advances in these areas has been remarkable and the wide band gap community relies on. I am looking for a program that will convert zno files to. Porter,2 and shashank priya1,a 1bioinspired materials and devices laboratory bmdl, center for energy harvesting materials and systems cehms, virginia tech, blacksburg, virginia 24061, usa. Highlevelfedoped ptype zno nanowire arrayngan film. Synthesis and characterization of zno nanostructures. Yicheng lu winlab electrical and computer engineering dept. Growth and characterization of zno based semiconductor.
Zno has received much attention over the past few years because it has a wide range of properties that depend on doping, including a range of conductivity from metallic to insulating including ntype and ptype conductivity, high transparency, piezoelectricity, widebandgap semiconductivity, roomtemperature ferromagnetism, and huge magnetooptic and chemical. Synopsis synthesis and characterization of zinc oxide zno. Department of computer science and engineering national institute of technology, rourkela rourkela769 008, orissa, india certi cate this is to certify that the thesis entitled, synthesis. Correlation between photoluminescence spectra with gas. Controlled synthesis and application of zno nanoparticles. Zno is a third generation of semiconductor, it can be prepared into various forms of films and nanostructures, and they have excellent optical properties, electrical properties and magnetic properties. Direct photogeneration of charge transfer ct exciton in organic and hybrid absorbers can overcome this problem to pave the avenue towards 20% efficiency with solutionbased materials.
Our intent was to achieve practical plasma etching processes, to understand the role of hydrogen in zno. Zinc oxide tetrapods znot, which exhibit threedimensional 3d shapes, are of major importance from a technological applications point of view, and thus efficient techniques for growth of different. Different mixtures of zno nanocrystals with cs 2 mo 6 i 8 ooc 2 f 5 6 cluster compound cmif dispersed into polyvinylpyrrolidone matrix have been prepared by very simple and low cost solution. In this work, the polystyrene was employed to fabrication and iv characterization of zno nanorod based metalinsulatorsemiconductor junction le hong quang2, chua soo jin2, eugene a.
Shubra singh 1,2,3, p thiyagarajan 1,2, k mohan kant 1,2, d anita 1,2, s thirupathiah 1,2, n rama 1,2, brajesh tiwari 1,2, m kottaisamy 2 and m s ramachandra rao 1,2,3. Xray diffraction xrd analysis reveals that inncodoped zno. In nanotechnology,the primary role of classical physical principles is replaced as molecular and. Zno nanostructures, defects, and devices the interest in zno structures has increased drastically in recent years. Nonpolar zno thin films and led devices scientific. Characteristics of znobased semiconductor ceramics doped. Properties of isotype nznongan heterostructures studied. Numerous kinds of photocatalysts such as oxide, nitride or sulfidebased semiconductors, conducting polymers or graphene oxidebased materials have emerged since the discovery of water splitting on tio2 electrodes in 1972. The semiconductor zno has gained substantial interest in the research community in part because of its large exciton binding energy 60 mev which could lead to lasing action based on exciton recombination even above room temperature. The research work presented in this dissertation is based on two direct and wide band gap semiconductors. Synthesis and characterization of zno nanoparticles of.
This paper presents the morphology, microstructure, optical and electrical properties of zno nanoparticles, zno nonorods with uv and ozone sensing response at room temperature and al. In the past two decades, the heteroepitaxy of gan q. Thermal conductivity of selfassembled nanostructured zno. Correlation between photoluminescence spectra with gas sensing and photocatalytic activities in hierarchical zno nanostructures t. The znobased nanostructured materials are considered as key materials for nanodevices fabrication. Intense research by many different groups has focused on novel nanostructures with different shapes ranging from nanowires to nanobelts and even nanosprings. Growth of freestanding nano and microstructures with complex morphologies is a highly desired aspect for real applications of nanoscale materials in various technologies. Investigating the effect of materials processing on zno nanorod properties and device performance sabina hatch degree of doctor of philosophy school of engineering and material science supervisor. Structure, microstructure and physical properties of zno. Ptype zno is a possible approach to achieve a wled device. Find answers to i am looking for a program that will convert zno files to pdf from the expert community at experts exchange. Gan and zno based materials and devices qian sun, jung han auth.
This content was uploaded by our users and we assume good faith they have the permission to share this book. Structure, microstructure and physical properties of zno based materials in various forms. The effect of mechanical stirring on solgel synthesis of thornlike zno nanoparticles znonps and antimicrobial activities is successfully reported in this study. Besides these established applications, zno and its ternary alloys are now also being considered as potential materials for. New design of zno nanorod and nanowirebased no2 room. Investigations on the cosputtered itozno transparent. Zno based materials system have attracted lots of attention because of their broad range applications in optoelectronics devices such as light emitting diode, photodetectors, solarcell etc. For example, by alloying with mgcd, doped zno can exhibit ptype conductivity. Gan and zno are important semiconductor materials with applications in blue and ultraviolet. Schematic diagram representing the crystalfield and spinorbit splitting of the valance band of zno into 3 sub band states a, b and c at 4. Fabrication and characterization of zno and gan devices. Gan and znobased materials and devices springerlink. Spincoated nzno films on inngansi wafers were converted to ptype polarity after thermal treatment of proper annealing durations.
Review of ganzno hybrid structures based materials and. Pdf we report on the characteristics of a zno lightemitting diode led comprised of a heterostructure of pzno n gan. Materials science and engineering our study focused on process development for znobased devices. An existential study on structural, optical and electronic. Abstract this paper presents the recent advances of the zinc oxide zno based nanowires and nanorods devices. Gan and znobased materials and devices with 328 figures 123. Overview of zno based materials and device research at. Although pzno growth technology is still a hotly debated issue, development of zno heterojunction based devices is of interest nonetheless because such devices have advantages over the homojunction devices owing to carrier and optical confinement, lower diffraction losses, and reduction of threshold current in injection devices. Characteristics of znobased semiconductor ceramics doped with geo2 and pbo. Gan and znobased materials and devices springer series in materials science. It was reported that these materials are highly sensitive to nox with the sensitivity further enhanced by adding precious group metals pgm such as pt, pd, au, etc. Furthermore, one of the biggest challenges for good znobased optoelectronic devices is the difficulty of reliably fabricating ptype zno due to its selfcompensating effect from native defects, such as oxygen vacancy v o, zinc interstitial zn i and h incorporation. An existential study on structural, optical and electronic properties of zno nanoparticles and.
Even though research focusing on zno goes back many decades, the renewed interest is fueled by availability of highquality. Synthesis and characterization of zno nanoparticles. Near ultraviolet light emitting diode composed of ngan. High sensitivity of no gas sensors based on novel agdoped. Investigating the effect of materials processing on zno. Fitzgerald1 1 massachusetts institute of technology. Thermal conductivity of selfassembled nanostructured zno bulk ceramics yu zhao,1,a yongke yan,1 ashok kumar,1 hsin wang,2 wallace d. On the irst fpart of the dissertation, the synthesis of zno nanorod array via the low temperature solution growth method on flexible in 2o 3pet and rigid itoglass substrates were discussed. Gan and znobased materials and devices springer series in materials science pearton, stephen on.
We then present the theory of doping and native defects in zno based on densityfunctional calculations. Direct growth of freestanding zno tetrapod networks for. These ito n gan and itozno n gan contact systems were then rapidly annealed at 100, 200, and 300 c, respectively, for 1 min under vacuum ambient. Gan and znobased materials and devices qian sun, jung. Roomtemperature gas sensors are attracting attention because of their low power consumption, safe operation, and longterm stability. Herein, zno nanorods nrs and nanowires nws were onchip grown via a facile hydrothermal method and used for roomtemperature no 2 gas sensor applications.
Yet, metaloxides are still largely the main family of materials promoted into photocatalytic applications. Gan and zno have gained substantial interest in the research area of wide bandgap semiconductors due to their unique electrical, optical and structural properties. Process development for znobased devices by kelly pui sze ip august 2005 chair. From the table we observe that oxide semiconductors viz. The zno nrs were obtained by a onestep hydrothermal process, whereas the. Novel znobased ternary oxides for optoelectronic applications mareike trunk. However, violetblue emissions dominated the led devices owing to the intrinsic direct emission of zno and gan, and absence of deeplevel emissions. Near ultraviolet light emitting diode composed of nganzno coaxial nanorod heterostructures on a pgan layer sung jin an and gyuchul yia national cri center for semiconductor nanorods and department of materials science and engineering. Even though research focusing on zno goes back many decades. Growth and characterization of zno based semiconductor materials and devices by ming wei b.
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